Solid Lubricant Additives

WS₂ Solid Lubricant Additives for Extreme Pressure Applications

Tungsten Disulfide (WS₂) solid lubricant additives for grease, oil, and coating formulation. Sub-micron dispersion. Engineered for EP, AW, and AF performance.

Material Science

What Is Tungsten Disulfide (WS₂)?

Tungsten Disulfide (WS₂, CAS 12138-09-9) is an inorganic compound with a hexagonal lamellar crystal structure where tungsten atoms are sandwiched between two sulfur layers. Van der Waals forces between planes allow individual layers to slide with minimal resistance — producing a dry COF of 0.03 under sliding contact.

Under tribological stress, WS₂ particles deposit on metal surfaces to form a coherent tribofilm that provides sustained EP and AW protection even when the bulk lubricant film is displaced. The tribofilm remains stable across a wide temperature range, making WS₂ effective where conventional additives fail.

Powderful Solutions supplies WS₂ in two engineered forms:

Solidex W004 — Dry Powder

Ultra-pure WS₂ powder, D50 = 0.4 μm, 99.9% purity. Direct blending into grease, coatings, and polymer composites.

Lubricore W850 — Pre-Dispersed

50% WS₂ in PAO-6. Surface-modified, sub-micron, stabilized. Drop-in additive for gear oils and engine oils.

Performance

Why WS₂ Matters: Performance That Drives Formulation Decisions

Friction Reduction

COF as low as 0.03 under dry sliding. In lubricated systems, reduces boundary friction by 30–60% vs. base lubricant alone.

Wear Reduction

4-Ball wear scar reduced 40–65% at equivalent treat rates vs. unfilled base oils (ASTM D4172).

Extreme Pressure

Weld point >300,000 PSI. Consistent EP performance at 1–3 wt% in grease (ASTM D2783).

Thermal Stability

Stable from −270°C to 650°C in air; up to 1,100°C in vacuum. No decomposition at normal industrial temperatures.

Humidity Resistance

Superior to MoS₂ in humid environments. Does not oxidize to corrosive species under atmospheric conditions.

Vacuum Compatibility

Maintains lubrication in vacuum — critical for aerospace mechanisms, satellite components, and vacuum process equipment.

Competitive Analysis

WS₂ vs. Alternatives

PropertyWS₂MoS₂PTFEGraphite
COF (dry)0.030.05–0.100.04–0.100.10–0.20
Max Temp (air)650°C350°C260°C450°C
Load (PSI)300,000+250,00030,00080,000
PFAS-Free
HumidityExcellentPoorExcellentRequires moisture
WS₂ outperforms PTFE with zero PFAS. As EU REACH and US EPA PFAS regulations tighten, WS₂ delivers equivalent or superior performance in a fully fluorine-free formulation.
Products

WS₂ Products from Powderful Solutions

Solidex W004 — WS₂ Dry Powder
CAS 12138-09-9 | D50 = 0.4 μm | 99.9% purity
Purity: 99.9%D50: 0.4 μmForm: Dry PowderPacks: 1–25 kg

Ultra-pure sub-micron WS₂ powder for direct blending into grease bases, dry film coatings, polymer composites, and tribological coatings.

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Lubricore W850 — WS₂ in PAO-6
CAS 12138-09-9 | 50% WS₂ in PAO-6 | Sub-micron, stabilized
Active: 50% WS₂Carrier: PAO-6Particle: Sub-micronPacks: 1–200 L

Pre-dispersed, surface-modified WS₂ concentrate. Ready to blend into engine oils, gear oils, hydraulic fluids. Eliminates agglomeration and filter-clogging.

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Applications

Where WS₂ Delivers Proven Performance

Industrial Greases

1–5 wt% in NLGI 2–3 greases increases weld point and reduces wear in heavily loaded bearings, cam followers, and joint assemblies.

Engine Oils

Forms tribofilm on cylinder walls and camshaft lobes. Reduces boundary friction during cold starts when hydrodynamic lubrication is incomplete.

Gear Oils

Critical for hypoid and spiral bevel gears. WS₂ tribofilm survives extreme flash temperatures that deplete conventional EP additive packages.

Mining Equipment

Pin-and-bushing joints, sheave bearings, and crusher bearings benefit from WS₂ hardness and EP performance under abrasive, high-load conditions.

Heavy-Duty Equipment

Articulation pins, bucket pivots, and tillage equipment run under oscillating high loads where WS₂ dispersions reduce fretting wear.

Aerospace & Defense

Maintains lubrication in vacuum — required for spacecraft mechanisms and satellite deployment systems where MoS₂ and graphite require atmospheric oxygen.

Technical FAQ

Frequently Asked Questions

What is WS₂ used for in lubricant formulations?
WS₂ functions as a solid lubricant additive in grease, engine oil, gear oil, hydraulic fluid, and dry film coating formulations. Primary roles are extreme pressure (EP) protection, anti-wear (AW) performance, and friction reduction (AF). Effective in high contact pressure, elevated temperature, and vacuum environments where liquid lubricants alone are insufficient.
Is WS₂ better than MoS₂ for grease additives?
WS₂ achieves lower COF (0.03 vs. 0.05–0.10), higher temperature stability (650°C vs. 350°C in air), and better humidity resistance. MoS₂ oxidizes to mildly corrosive MoO₃ in humid environments; WS₂ does not. For aerospace and humid industrial applications, WS₂ is generally preferred. MoS₂ remains competitive in cost-sensitive, controlled-humidity applications.
What particle size of WS₂ is best for oil additives?
Sub-micron (D50 ≤ 0.5 μm) is required for engine oils, gear oils, and hydraulic fluids where EHD film thickness is 0.1–1.0 μm. Particles larger than the film thickness cause abrasive wear rather than lubrication. Lubricore W850 uses surface-modified sub-micron WS₂ optimized for oil carrier systems.
Can WS₂ replace PTFE in lubricant formulations?
Yes. WS₂ delivers lower COF (0.03 vs. 0.04–0.10), significantly higher load capacity (300,000 PSI vs. ~30,000 PSI), wider temperature range, and contains zero fluorine — fully compliant with EU REACH and US EPA PFAS regulations. Treat rate adjustments required when transitioning; our technical team provides reformulation guidance.
What is the recommended treat rate for WS₂ in grease?
Typically 1–5 wt%. For general EP greases (NLGI 2), 1–2 wt% measurably increases weld point and reduces wear scar. For mining, articulated loader joints, or heavy bearings, 3–5 wt% is common. Above 5 wt% rarely yields proportional gains. Validate with ASTM D2266 and D2783 testing on the specific grease matrix.

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Our technical team works directly with lubricant formulators to optimize particle size, concentration, and carrier system for your application.

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